• 文献标题:   Molybdenum oxide-iron oxide/graphene composite as anode materials for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   CHEN SS, QIN X
  • 作者关键词:   molybdenum oxide, iron oxide, graphene, anode material, lithium ion batterie
  • 出版物名称:   JOURNAL OF SOLID STATE ELECTROCHEMISTRY
  • ISSN:   1432-8488 EI 1433-0768
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   0
  • DOI:   10.1007/s10008-015-2846-3
  • 出版年:   2015

▎ 摘  要

Molybdenum oxide-iron oxide/graphene (MoO2-Fe3O4/G) ternary nanocomposite is firstly prepared as for an anode material for lithium ion batteries. The MoO2-Fe3O4/G hybrid electrode exhibits a high specific capacity, long cycle life, and good rate capability. The initial charge specific capacity is 922.0 mAh g(-1) of MoO2-Fe3O4/G nanocomposite and it increases to 1154.9 mAh g(-1) gradually after 100 cycles, which is 125 % comparing to the initial charge capacity. The conductive graphene and Fe3O4 nanoparticles facilitate the conductivity of electrons and the diffusion of lithium-ions by shortening the transport distance. Additionally, the graphene and Fe3O4 not only work as a mechanical support to buffer the volume changes but also protect the MoO2 crystals from agglomeration during lithium ion intercalation/de-intercalation. The results demonstrate that the MoO2-Fe3O4/G nanocomposite is a promising alternative anode material for practical Li-ion batteries.