• 文献标题:   Scalable synthesis of SnS2/S-doped graphene composites for superior Li/Na-ion batteries
  • 文献类型:   Article
  • 作  者:   ZHENG PL, DAI ZF, ZHANG Y, DINH KN, ZHENG Y, FAN HS, YANG J, DANGOL R, LI B, ZONG Y, YAN QY, LIU XB
  • 作者关键词:  
  • 出版物名称:   NANOSCALE
  • ISSN:   2040-3364 EI 2040-3372
  • 通讯作者地址:   Univ Elect Sci Technol China
  • 被引频次:   37
  • DOI:   10.1039/c7nr06044k
  • 出版年:   2017

▎ 摘  要

Tin disulfide (SnS2) has emerged as a promising anode material for lithium/sodium ion batteries (LIBs/SIBs) due to its unique layered structure, outstanding electrochemical properties and low cost. However, its poor cycling life and time-consuming synthesis as well as low-yield production hinder the practical utilization of nanostructured SnS2. In this work, we demonstrate a simple and reliable dissolution-regeneration strategy to construct a flexible SnS2/sulfur-doped reduced graphene oxide (S-rGO) composite as anodes for LIBs and SIBs, highlighting its mass-production feature. In addition, the robust affinity between SnS2 and S-rGO without interstitial volume is very beneficial for preventing the SnS2 particles from breaking themselves away from the rGO nanosheets into free nanoparticles. As a result, the SnS2/S-rGO composite as anodes delivers high reversible capacities of 1078 mA h g(-1) and 564 mA h g(-1) (at 0.1 A g(-1)) for LIBs and SIBs, respectively, and excellent rate capabilities and cycling stability (e.g. 532 mA h g(-1) during the 600 cycles at 5.0 A g (1) for LIBs). Our proposed strategy may also possess great potential for the practical application of other electrochemically active metal sulfide composites for energy devices.