• 文献标题:   Mechanical and dynamic-mechanical properties of silanized graphene oxide/epoxy composites
  • 文献类型:   Article
  • 作  者:   LAVORATTI A, ZATTERA AJ, AMICO SC
  • 作者关键词:   epoxy resin, graphene oxide, composite, silane
  • 出版物名称:   JOURNAL OF POLYMER RESEARCH
  • ISSN:   1022-9760 EI 1572-8935
  • 通讯作者地址:   Univ Fed Rio Grande do Sul
  • 被引频次:   6
  • DOI:   10.1007/s10965-019-1805-6
  • 出版年:   2019

▎ 摘  要

Epoxy resins are widely used thermosets due to their excellent mechanical properties, but their highly cross-linked network hinders their impact absorption ability and limited fracture toughness. Aiming to improve those characteristics, graphene oxide has emerged as a potential nanofiller for epoxy, and additional gain can be achieved with its functionalization. This study focuses on the influence of the GO treatment with 3-aminopropyltriethoxysilane (APTES) on the viscosity, curing behavior, cross-link density and mechanical and dynamic-mechanical properties of GO/epoxy nanocomposites. At only 0.10wt% of GO, cross-link density and heat of reaction were reduced, and the glass transition temperature increased by 7 degrees C in comparison to the neat resin. Additionally, the plane-strain fracture toughness increased for 0.10wt% GO and for all APTES treated GO, which represents an advantage in the large-scale use of epoxy composites.