• 文献标题:   High specific surface area porous graphene grids carbon as anode materials for sodium ion batteries
  • 文献类型:   Article
  • 作  者:   ZHANG H, GUO HN, LI AY, CHANG XY, LIU S, LIU D, WANG YJ, ZHANG F, YUAN HT
  • 作者关键词:   carbonbased material, porous structure, ultrahigh surface area, ag nanoparticle, sodium ion battery
  • 出版物名称:   JOURNAL OF ENERGY CHEMISTRY
  • ISSN:   2095-4956
  • 通讯作者地址:   Nankai Univ
  • 被引频次:   12
  • DOI:   10.1016/j.jechem.2018.06.002
  • 出版年:   2019

▎ 摘  要

Although great accomplishments of functional material synthesis have been achieved in sodium ion batteries (SIBs) recently, there are still numerous challenges and problems in preparing carbon-based materials with porous architectures and enough lattice distance for Na+ insertion. Herein we report a templated strategy to synthesize 3D porous graphene girds (PGGs) consisting of several stacking graphene structure with ultrahigh surface area and hierarchical connected structure by employing Ag nanopartides (NPs). The Ag NPs will regenerate for decreasing the experimental cost, also in line with principles of green chemistry and environmentally friendly strategy. The PGGs obtain advanced specific capacity of 160 mA h g(-1) at current density of 50 mA h g(-1). Moreover, 112 mA h g(-1) capacity can be gained at 1 A h g(-1) during 1000 cycles. Due to their porous architecture, ultrahigh surface area and low amorphous graphited structure, PGGs electrode showed the excellent electrochemical performance in high rate capability. (C) 2018 Science Press and Dalian Institute of Chemical Physics, Chinese Academy of Sciences. Published by Elsevier B.V. and Science Press. All rights reserved.