• 文献标题:   Luminescence properties of boron and nitrogen doped graphene quantum dots prepared from arc-discharge-generated doped graphene samples
  • 文献类型:   Article
  • 作  者:   DEY S, GOVINDARAJ A, BISWAS K, RAO CNR
  • 作者关键词:  
  • 出版物名称:   CHEMICAL PHYSICS LETTERS
  • ISSN:   0009-2614 EI 1873-4448
  • 通讯作者地址:   JNCASR
  • 被引频次:   84
  • DOI:   10.1016/j.cplett.2014.02.012
  • 出版年:   2014

▎ 摘  要

Substitution of heteroatoms in graphene is known to tailor its band gap. Another approach to alter the band gap of graphene is to create zero-dimensional graphene quantum dots (GQDs). Here we present the synthesis and photoluminescence properties of B-doped graphene quantum dots (B-GQDs) for the first time, having prepared the B-GQDs by chemical scissoring of B-doped graphene generated by arcdischarge in gas phase. We compare the photoluminescence properties of B-GQDs with nitrogen-doped GQDs and pristine GQDs. Besides, excitation wavelength independent PL emission, excellent upconversion of PL emission is observed in GQDs as well as B-and N-doped GQDs. (C) 2014 Elsevier B.V. All rights reserved.