• 文献标题:   Flexible and free-standing ternary Cd2GeO4 nanowire/graphene oxide/CNT nanocomposite film with improved lithium ion battery performance
  • 文献类型:   Article
  • 作  者:   WANG LL, ZHANG XZ, SHEN GZ, PENG X, ZHANG M, XU JL
  • 作者关键词:   flexibility, lithium battery, cd2geo4 nw/go/cnt
  • 出版物名称:   NANOTECHNOLOGY
  • ISSN:   0957-4484 EI 1361-6528
  • 通讯作者地址:   Shanghai Univ Engn Sci
  • 被引频次:   3
  • DOI:   10.1088/0957-4484/27/9/095602
  • 出版年:   2016

▎ 摘  要

To realize flexible lithium-ion batteries (LIBs), the design of flexible electrode/current collector materials with high mechanical flexibility, superior conductivity and excellent electrochemical performance and electrical stability are highly desirable. In this work, we developed a new ternary Cd2GeO4 nanowire/graphene oxide/carbon nanotube nanocomposite (Cd2GeO4 NW/GO/CNT) film electrode. Benefiting from the efficient combination of GO and Cd2GeO4 NWs, our Cd2GeO4 NW/GO/CNT composite film exhibits a capacity of 784 mA h g(-1) after 30 cycles at 200 mA g(-1), which is 2.7 times higher than that of Cd2GeO4 NW/CNT film (290 mA h g(-1)). At a higher rate of 400 mA g(-1) and 1 A g(-1), the Cd2GeO4 NW/GO/CNT film delivers a stable capacity of 617 and 397 mA h g(-1), respectively. Even at 2.5 A g(-1), it still exhibits a high rate capacity of 180 mA h g(-1). The flexible Cd2GeO4 NW/GO/CNT film clearly demonstrates good cycling stability and rate performance for anode materials in LIBs. This route may be extended to design other flexible free-standing metal germanate nanocomposite anode materials.