• 文献标题:   Equilibrium and kinetics studies for the adsorption of Ni2+ and Fe3+ ions from aqueous solution by graphene oxide
  • 文献类型:   Article
  • 作  者:   KONICKI W, ALEKSANDRZAK M, MIJOWSKA E
  • 作者关键词:   nickel, iron, graphene oxide, adsorption, kinetic
  • 出版物名称:   POLISH JOURNAL OF CHEMICAL TECHNOLOGY
  • ISSN:   1509-8117 EI 1899-4741
  • 通讯作者地址:   Maritime Univ Szczecin
  • 被引频次:   6
  • DOI:   10.1515/pjct-2017-0058
  • 出版年:   2017

▎ 摘  要

In this study, the adsorption of Ni2(+) and Fe3(+) metal ions from aqueous solutions onto graphene oxide ( GO) have been explored. The effects of various experimental factors such as pH of the solution, initial metal ion concentration and temperature were evaluated. The kinetic, equilibrium and thermodynamic studies were also investigated. The adsorption rate data were analyzed using the pseudo-first-order kinetic model, the pseudo-second-order kinetic model and the intraparticle diffusion model. Kinetic studies indicate that the adsorption of both ions follows the pseudo-second-order kinetics. The isotherms of adsorption data were analyzed by adsorption isotherm models such as Langmuir and Freundlich. Equilibrium data fitted well with the Langmuir model. The maximum adsorption capacities of Ni2(+) and Fe3(+) onto GO were 35.6 and 27.3 mg g(-1), respectively. In addition, various thermodynamic parameters, such as enthalpy (Delta HO), entropy (Delta SO) and Gibbs free energy (Delta GO), were calculated.