• 文献标题:   Green and facile preparation of graphene/resveratrol/polyaniline composites for high-performance supercapacitors
  • 文献类型:   Article
  • 作  者:   WANG ZK, JIANG LC, PAN HW, CUI YY, ZONG CZ
  • 作者关键词:  
  • 出版物名称:   NEW JOURNAL OF CHEMISTRY
  • ISSN:   1144-0546 EI 1369-9261
  • 通讯作者地址:  
  • 被引频次:   0
  • DOI:   10.1039/d0nj04739b
  • 出版年:   2021

▎ 摘  要

In recent years, graphene-based supercapacitors have become one of the most promising new energy devices. However, the re-stacking of graphene during the preparation process and the toxicity of reducing agents limit its further development. Therefore, in this work, we used resveratrol (RA), a novel and green reducing agent, to prepare reduced graphene oxide (rGO). The results of X-ray diffraction (XRD), ultraviolet-visible (UV-vis) spectroscopy and Raman spectroscopy proved that the reducing effect of RA is equivalent to that of hydrazine hydrate (HH). Subsequently, the composite was prepared and cyclic voltammetry (CV) and galvanostatic charge-discharge (GCD) tests were conducted to study the electrochemical performance. The results show that the composite reduced by RA for 24 hours exhibits the largest specific capacitance (916 F g(-1) at 1 A g(-1)), which is higher than that of the composite reduced by HH (822 F g(-1) at 1 A g(-1)), and has the best rate performance and stable cycle performance (retention rate is 87.24% after 10 000 cycles). A symmetric supercapacitor was assembled with the obtained composites reduced by RA exhibiting a maximum specific capacitance of 461 F g(-1) at 1 A g(-1), an energy density of 31.38 W h kg(-1) at 0.701 kW kg(-1), and ultrahigh-rate performance (retained 61.4% capacitance at 40 A g(-1)).