• 文献标题:   Role of graphene oxide/yttrium oxide nanocomposites as a cathode material for natural dye-sensitized solar cell applications
  • 文献类型:   Article, Early Access
  • 作  者:   SHANMUGAPRIYA T, BALAVIJAYALAKSHMI J
  • 作者关键词:   graphene, uv #8211, vis i #8211, v, yttrium oxide
  • 出版物名称:   ASIAPACIFIC JOURNAL OF CHEMICAL ENGINEERING
  • ISSN:   1932-2135 EI 1932-2143
  • 通讯作者地址:   PSGR Krishnammal Coll Women
  • 被引频次:   0
  • DOI:   10.1002/apj.2598 EA NOV 2020
  • 出版年:  

▎ 摘  要

Natural dye-sensitized solar cells (DSSCs) are becoming promising candidates for replacing synthetic dyes. Graphene oxide is prepared from natural graphite flakes by modified Hummers method. A novel graphene oxide/yttrium oxide (GO/Y2O3) nanocomposites are prepared by chemical precipitation method. The different concentration of (5:1, 5:2, and 5:3) of yttrium oxide nanoparticles exaggerated on the surface of graphene oxide nanosheets. The prepared nanocomposites are characterized by X-ray diffraction (XRD), scanning electron microscopy (SEM), high-resolution transmission electron microscopy (HR-TEM), energy-dispersive X-ray spectroscopy (EDAX), Fourier transform infrared spectroscopy (FT-IR), Raman scattering spectroscopy and ultraviolet-visible (UV-vis) absorption spectroscopy. The XRD analysis showed that the crystallite size of the GO/Y2O3 (5:1, 5:2, and 5:3) is found to be around 23, 25.2, and 26.92 nm. Field emission scanning electron microscopy (FE-SEM) revealed that the flakes like shaped yttrium oxide nanoparticles are uniformly dispersed on the surface of GO sheets. The UV-vis studies showed that the prepared Jasminoum grandiflorum L (JG) dye belongs to chlorophyll group with the absorption of 4.2 eV. The electrochemical activity of the prepared nanocomposites is investigated by cyclic voltammetry (CV) technique. The power conversion efficiency of prepared sandwich type DSSCs (5:3) is found to be 1.67%.