• 文献标题:   Glassy carbon electrode modified with a film composed of Ni(II), quercetin and graphene for enzyme-less sensing of glucose
  • 文献类型:   Article
  • 作  者:   SUN JY, HUANG KJ, FAN Y, WU ZW, LI DD
  • 作者关键词:   glucose, quercetin, graphene, chemicallymodified electrode, electrocatalysi
  • 出版物名称:   MICROCHIMICA ACTA
  • ISSN:   0026-3672 EI 1436-5073
  • 通讯作者地址:   Xinyang Normal Univ
  • 被引频次:   17
  • DOI:   10.1007/s00604-011-0625-0
  • 出版年:   2011

▎ 摘  要

We present a modified glassy carbon electrode as a sensing platform for glucose. It is based on a composite film prepared from Ni(II) ion, quercetin and graphene. The sensor was characterized by cyclic voltammetry. The electron transfer coefficient, reaction rate constant and catalytic rate constant were determined and found to be 0.53, 5.4 s(-1) and 2.93 x 10(3) M-1 s(-1), respectively. The catalytic current depends linearly on the concentration of glucose in the range from 3 to 900 mu M, with a detection limit of 0.5 mu M (at an S/R of 3). The sensor exhibits good reproducibility, stability, fast response, and high sensitivity.