• 文献标题:   Decoration of Graphene Oxide Sheets with Luminescent Heteronuclear Rare-Earth Complexes
  • 文献类型:   Article
  • 作  者:   LI YT, QIU S, DU T, WEI W, HAN ZB, RUAN FY, CAO LH
  • 作者关键词:   graphene oxide, samarium, rare earth, luminescence
  • 出版物名称:   CHINESE JOURNAL OF INORGANIC CHEMISTRY
  • ISSN:   1001-4861
  • 通讯作者地址:   Shaanxi Univ Sci Technol
  • 被引频次:   0
  • DOI:   10.11862/CJIC.2019.016
  • 出版年:   2019

▎ 摘  要

A novel high luminescent performance of graphene oxide-rare earth hybrid material was prepared using a noncovalent approach. Herein, a heteronuclear rare earth complex were revealed in which the benzoic acid (BA) and 1,10-phenanthroline hydrate (Phen) coordinated with Sm3+ and Gd3+, which was used to functionalize graphene oxide sheets (GOSs). The as-prepared products were characterized via Fourier-transform infrared spectroscopy, X-ray diffraction, scanning electron microscope, fluorescence spectrometer, decay lifetime and thermogravimetric analysis. The hybrid materials exhibited strong luminescence intensity, long lifetime and good thermal stability. Besides, Gd3+ ions had a strong sensitizing effect on materials and played a significant role in improving the luminescence intensity. The presence of GOSs did not quench the fluorescence performance of hybrid materials. Moreover, their fluorescence properties of Sm3+ and Gd3+ with different molar ratios were also studied.