• 文献标题:   Preparation and Physical Properties of Waterborne Polyurethane/Functionalized Graphene Sheet Nanocomposites
  • 文献类型:   Article
  • 作  者:   RAGHU AV, LEE YR, JEONG HM, SHIN CM
  • 作者关键词:   conductivity, graphene, mechanical propertie, nanocomposite, polyurethane
  • 出版物名称:   MACROMOLECULAR CHEMISTRY PHYSICS
  • ISSN:   1022-1352 EI 1521-3935
  • 通讯作者地址:   Univ Ulsan
  • 被引频次:   176
  • DOI:   10.1002/macp.200800395
  • 出版年:   2008

▎ 摘  要

A nanocomposite of waterborne polyurethane (WPU) was prepared with functionalized graphene sheets (FGSs) which are a new type of nano-sized conductive filler. The FIGS were finely dispersed in a polymer matrix to improve the conductivity of the WPU. Conductivity of about 105 times that of pristine WPU was attained using two parts FIGS per. 100 parts of the matrix polymer. The FGS reduced the hard segment crystallinity of the WPU, which lowered the modulus of the WPU at room temperature. This modulus reduction became more evident in the temperature region above the glass transition temperature of the hard segment.