▎ 摘 要
Herein, N doped graphene quantum dots-interspersed Cadmium tungstate (CdWO4) nanorods (N-GQDs-CdWO4) were synthesized via decorating the N-GQDs on the surface of CdWO4 nanorods in three steps. The morphological and structural properties of the N-GQDs-CdWO4 nanorods were thoroughly investigated by X-ray diffraction spectroscopy, field-emission scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, Fourier Transform infrared spectroscopy, Raman spectroscopy, and ultravioletevisible spectroscopy. Based on imaging techniques, it became clear that the N-GQDs decorated on the surface of CdWO4 nanorods formed a heterostructure. This nanocomposite exhibits enhanced photoelectrochemical performancesdmore than four times those of bare CdWO4. In addition, the nanocomposite's photocatalytic activity under ultra-violet light irradiation was almost six fold that of bare CdWO4. We studied the mechanism governing its exceptional performance. It indicates that the existence of a heterostructure induces a synergistic effect between the N-GQDs and CdWO4 nanorods that bolsters photoelectric performance. Our work provides a feasible method to synthesize 0D/3D nanocomposites with enhanced photoelectrochemical performances, and offers a solution to rectify current solar energy shortfalls. (C) 2017 Published by Elsevier B.V.