• 文献标题:   Synthesis of N doped graphene quantum dots-interspersed CdWO4 heterostructure nanorods as an effective photocatalyst with enhanced photoelectrochemical performance
  • 文献类型:   Article
  • 作  者:   PEI Y, FAN T, CHU H, GE YC, YANG Y, DONG P, BAINES R, YE MX, SHEN JF
  • 作者关键词:   n doped graphene quantum dot, cdwo4 nanorod, hydrothermal method, photocatalyst
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Fudan Univ
  • 被引频次:   8
  • DOI:   10.1016/j.jallcom.2017.05.237
  • 出版年:   2017

▎ 摘  要

Herein, N doped graphene quantum dots-interspersed Cadmium tungstate (CdWO4) nanorods (N-GQDs-CdWO4) were synthesized via decorating the N-GQDs on the surface of CdWO4 nanorods in three steps. The morphological and structural properties of the N-GQDs-CdWO4 nanorods were thoroughly investigated by X-ray diffraction spectroscopy, field-emission scanning electron microscopy, transmission electron microscopy, X-ray photoelectron spectroscopy, Fourier Transform infrared spectroscopy, Raman spectroscopy, and ultravioletevisible spectroscopy. Based on imaging techniques, it became clear that the N-GQDs decorated on the surface of CdWO4 nanorods formed a heterostructure. This nanocomposite exhibits enhanced photoelectrochemical performancesdmore than four times those of bare CdWO4. In addition, the nanocomposite's photocatalytic activity under ultra-violet light irradiation was almost six fold that of bare CdWO4. We studied the mechanism governing its exceptional performance. It indicates that the existence of a heterostructure induces a synergistic effect between the N-GQDs and CdWO4 nanorods that bolsters photoelectric performance. Our work provides a feasible method to synthesize 0D/3D nanocomposites with enhanced photoelectrochemical performances, and offers a solution to rectify current solar energy shortfalls. (C) 2017 Published by Elsevier B.V.