• 文献标题:   Synthesis of porous nitrogen-doped graphene decorated by gamma-Fe2O3 nanorings for enhancing microwave absorbing performance
  • 文献类型:   Article
  • 作  者:   WANG SS, JIAO QZ, SHI Q, ZHU HH, FENG TY, LU QL, FENG CH, LI HS, SHI DX, ZHAO Y
  • 作者关键词:   porous composite, nanoring, gammafe2o3, nitrogendoped graphene, microwave absorbing performance
  • 出版物名称:   CERAMICS INTERNATIONAL
  • ISSN:   0272-8842 EI 1873-3956
  • 通讯作者地址:   Beijing Inst Technol
  • 被引频次:   6
  • DOI:   10.1016/j.ceramint.2019.09.064
  • 出版年:   2020

▎ 摘  要

Excellent wave absorbers are key materials for reducing electromagnetic radiation pollution. In this work, novel gamma-Fe2O3 nanoring/porous nitrogen-doped graphene (gamma-Fe2O3 NR/PNG) composites with varying mass ratios were successfully synthesized as lightweight absorbers using a two-step solvothermal method in combination with a partial reduction process. The diameter of the uniform gamma-Fe2O3 NRs is approximately 150 nm with a shell thickness of approximately 50 nm. The uniform gamma-Fe2O3 NRs are dispersed onto PNG sheets. Compared with pure gamma-Fe2O3 NRs and PNG, all gamma-Fe2O3 NR/PNG composites exhibit better microwave absorbing performance, among which a gamma-Fe2O3 NR/PNG composite with a 4:1 mass ratio of gamma-Fe2O3 NR:PNG shows the best absorption over a broad bandwidth for its special nanoring and porous structure and excellent impedance matching. The minimum reflection loss (RLmin) reaches -40.18 dB at 7.80 GHz with a thickness of 2.5 mm; the absorption bandwidth (RL < -10 dB) is 3.41 GHz. Moreover, the composite also reveals a good absorption for microwaves in the low frequency range. At 3.38 GHz, RLmin reaches -32.69 dB with a thickness of 5.5 mm. This work provides guidance for designing absorbers that are lightweight, wideband with strong absorption.