• 文献标题:   Three-dimensional B,N-doped graphene foam as a metal-free catalyst for oxygen reduction reaction
  • 文献类型:   Article
  • 作  者:   XUE YH, YU DS, DAI LM, WANG RG, LI DQ, ROY A, LU F, CHEN H, LIU Y, QU J
  • 作者关键词:  
  • 出版物名称:   PHYSICAL CHEMISTRY CHEMICAL PHYSICS
  • ISSN:   1463-9076 EI 1463-9084
  • 通讯作者地址:   Wenzhou Med Coll
  • 被引频次:   195
  • DOI:   10.1039/c3cp51942b
  • 出版年:   2013

▎ 摘  要

Using a modified chemical vapor deposition (CVD) method, we have prepared a class of new graphene foams (GFs) doped with nitrogen, boron or both. Nitrogen-doped graphene foams (N-GFs) with a nitrogen doping level of 3.1 atom% were prepared by CVD of CH4 in the presence of NH3 while boron-doped graphene foams (B-GFs) with a boron doping level of 2.1 atom% were produced by using toluene and triethyl borate as a carbon and a boron source. On the other hand, graphene foams co-doped with nitrogen (4.5 atom%) and boron (3 atom%) (BN-GFs) were prepared by CVD using melamine diborate as the precursor. In all cases, scanning electron microscope (SEM) images revealed well-defined foam-like microstructures, while electrochemical measurements showed much higher electrocatalytic activities toward oxygen reduction reaction for the doped graphene foams than their undoped counterparts.