• 文献标题:   Quenching of [Ce(H2O)(n)](3+) Fluorescence by Graphene Oxide
  • 文献类型:   Article
  • 作  者:   KRUHLIK AS, MALASHKEVICH GE, POVEDAILO VA, RONISHENKO BV, TOLKACHEV VA, YAKOVLEV DL
  • 作者关键词:   cerium nitrate, graphene oxide, absorption spectrum, fluorescence, fluorescence quenching
  • 出版物名称:   JOURNAL OF APPLIED SPECTROSCOPY
  • ISSN:   0021-9037 EI 1573-8647
  • 通讯作者地址:   Natl Acad Sci Belarus
  • 被引频次:   0
  • DOI:   10.1007/s10812-019-00830-4
  • 出版年:   2019

▎ 摘  要

Static fluorescence quenching by graphene oxide at various concentrations was observed by measuring the relative fluorescence intensity and excited-state lifetime of optically excited Ce3+ ions in aqueous cerium nitrate solutions. The measured Stern-Volmer association constant of Ce aqua complexes with graphene oxide was 24.7 L/g, which was significantly less than the constants for cationic rhodamine dyes and metal cations and was explained by the negative charges on the interacting species.