• 文献标题:   Durability and Activity Tunable Pt/Graphene Catalyst for Oxygen Reduction Reactions
  • 文献类型:   Article
  • 作  者:   ZHANG P, TU WM, WANG R, CAI SC, WU J, YAN Q, PAN HF, ZHANG HN, TANG HL
  • 作者关键词:   durability, activity tunable, oxygen reduction reaction, micropore, graphene support
  • 出版物名称:   INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
  • ISSN:   1452-3981
  • 通讯作者地址:   Wuhan Univ Technol
  • 被引频次:   1
  • DOI:   10.20964/2016.12.89
  • 出版年:   2016

▎ 摘  要

We report durability and activity tunable Pt/graphene with micropores controllable graphene as the supports for oxygen reduction reactions. The graphene supports are prepared by thermal reduction of few-layered graphite oxide in hydrogen atmosphere. Oxygen atoms emission and carbon atoms rearrangement occur during the thermal reduction at variable temperature, thus form tunable micropores and graphitization degree in the graphene supports. Symmetrical dispersion of Pt nanoparticles with an medial diameter of 2.3 nm loaded on stable graphene supports contribute to a supernal electrochemical surface area, enhanced electrochemical catalytic activity and durability toward oxygen reduction reactions compared to mercantile Pt/C catalyst. The results demonstrate that durability and activity tunable Pt/graphene is a promising electrocatalyst for oxygen reduction in fuel cells.