• 文献标题:   Ternary manganese ferrite/graphene/polyaniline nanostructure with enhanced electrochemical capacitance performance
  • 文献类型:   Article
  • 作  者:   XIONG P, HU CY, FAN Y, ZHANG WY, ZHU JW, WANG X
  • 作者关键词:   manganese ferrite, graphene, polyaniline, ternary nanostructure, supercapacitor
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Nanjing Univ Sci Technol
  • 被引频次:   84
  • DOI:   10.1016/j.jpowsour.2014.05.048
  • 出版年:   2014

▎ 摘  要

A ternary manganese ferrite/graphene/polyaniline (MGP) nanostructure is designed and synthesized via a facile two-step approach. This nanostructure exhibits outstanding electrochemical performances, such as high specific capacitance (454.8 F g(-1) at 0.2 A g(-1)), excellent rate capability (75.8% capacity retention at 5 A g(-1)), and good cycling stability (76.4% capacity retention after 5000 cycles at 2 A g(-1)), which are superior to those of its individual components (manganese ferrite, reduced-graphene oxide, polyaniline) and corresponding binary hybrids (manganese ferrite/graphene (MG), manganese ferrite/polyaniline (MP), and graphene/polyaniline (GP)). A symmetric supercapacitor device using the as-obtained hybrid has been fabricated and tested. The device exhibits a high specific capacitance of 307.2 F g(-1) at 0.1 A g(-1) with a maximum energy density of 13.5W h kg. The high electrochemical performance of ternary MGP can be attributed to its well-designed nanostructure and the synergistic effect of the individual components. (C) 2014 Elsevier B.V. All rights reserved.