• 文献标题:   A novel monolithic Pd catalyst supported on cordierite with graphene coating
  • 文献类型:   Article
  • 作  者:   ZHU YC, YU LY, WANG XF, ZHOU YH, YE HQ
  • 作者关键词:   graphene oxide, graphene, cordierite, palladium catalyst, immobilization
  • 出版物名称:   CATALYSIS COMMUNICATIONS
  • ISSN:   1566-7367
  • 通讯作者地址:   Cent S Univ
  • 被引频次:   26
  • DOI:   10.1016/j.catcom.2013.06.018
  • 出版年:   2013

▎ 摘  要

Immobilization on a structured substrate is a prerequisite for exploiting practical applications for graphene as a catalytic support. Here we report that graphene oxide (GO) nanosheets can readily form a stable coating on a cordierite honeycomb substrate without any need of stabilizers. FT-IR and H-1 NMR characterization revealed that GO nanosheets were probably immobilized on the cordierite surface by hydrogen bonding. TEM analysis indicated that palladium particles loaded on the graphene/cordierite exhibited a uniform size of less than 5 nm, which led to 4 times higher activity for styrene hydrogenation than that loaded on the cordierite. (C) 2013 The Authors. Published by Elsevier B.V. All rights reserved.