• 文献标题:   Efficient Removal of Siloxane from Biogas by Using beta-Cyclodextrin-Modified Reduced Graphene Oxide Aerogels
  • 文献类型:   Article
  • 作  者:   ZHENG YH, HOU XF, LV SQ, MA ZC, MA XL
  • 作者关键词:   reduced graphene oxide aerogel, betacyclodextrin, hydrothermal reduction, hexamethyldisiloxane, contaminant removal
  • 出版物名称:   NANOMATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   2
  • DOI:   10.3390/nano12152643
  • 出版年:   2022

▎ 摘  要

In this study, beta-cyclodextrin-modified reduced graphene oxide aerogels (beta-CD-rGOAs) were synthesized via a one-step hydrothermal method and were used to remove hexamethyldisiloxane (L2) from biogas. The beta-CD-rGOAs were characterized by the Brunner-Emmet-Teller technique, using Fourier-transform infrared spectroscopy, Raman spectrometry, scanning electron microscopy (SEM), contact angle measurements, and X-ray diffraction. The results of the characterizations indicate that beta-CD was grafted onto the surface of rGOAs as a cross-linking modifier. The beta-CD-rGOA had a three-dimensional, cross-linked porous structure. The maximum breakthrough adsorption capacity of L2 on beta-CD-rGOA at 273 K was 111.8 mg g(-1). A low inlet concentration and bed temperature facilitated the adsorption of L2. Moreover, the beta-CD-rGOA was regenerated by annealing at 80 degrees C, which renders this a promising material for removing L2 from biogas.