• 文献标题:   Time-dependent protection of ground and polished Cu using graphene film
  • 文献类型:   Article
  • 作  者:   DONG YH, LIU QQ, ZHOU Q
  • 作者关键词:   copper, eis, sem
  • 出版物名称:   CORROSION SCIENCE
  • ISSN:   0010-938X EI 1879-0496
  • 通讯作者地址:   China Univ Petr
  • 被引频次:   17
  • DOI:   10.1016/j.corsci.2014.09.018
  • 出版年:   2015

▎ 摘  要

Graphene was deposited on Cu sheets with different morphologies by chemical vapor deposition. Scanning electron microscopy (SEM) analysis indicated that the morphology of the Cu sheet affected the graphene film properties. Electrochemical impedance spectroscopy measurements showed that the graphene film did not effectively protect Cu against corrosion because of prolonged exposure to ionic environments (3.5 wt.% NaCl solution). For short durations, graphene films provided better protection to polished Cu than ground Cu. Prolonged electrolyte immersion of graphene-coated Cu samples showed that the graphene film from the polished Cu surface was detached more easily than that from ground Cu. (C) 2014 Elsevier Ltd. All rights reserved.