• 文献标题:   Synthesis and electrochemical performance of LiFePO4/graphene composites by solid-state reaction
  • 文献类型:   Article
  • 作  者:   WANG Y, FENG ZS, CHEN JJ, ZHANG C
  • 作者关键词:   composite material, lifepo4, graphene, solidstate reaction, nanocomposite, lithiumion battery
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Univ Elect Sci Technol China
  • 被引频次:   68
  • DOI:   10.1016/j.matlet.2011.12.034
  • 出版年:   2012

▎ 摘  要

LiFePO4/graphene composites with graphene content of 5 wt.% were prepared by solid-state reaction. The composites were characterized by X-ray diffraction and scanning electron microscopy, and their electrochemical properties were investigated by galvanostatic charge and discharge tests. The experimental results show that a three-dimensional conducting network was formed by graphene sheets, which can improve the electronic conductivity of the composites. The LiFePO4/graphene composites exhibited an initial discharge capacity of 161 mAh g(-1) at 0.1 C and the capacity retained 70 mAh g(-1) even at high rate of 50 C. The composites are of great potential use as cathode material in high-power lithium-ion batteries for electric vehicles and hybrid-electric vehicles. (C) 2011 Elsevier B.V. All rights reserved.