• 文献标题:   High-sensitive electrochemical sensor of Sudan I based on template-directed self-assembly of graphene-ZnSe quantum dots hybrid structure
  • 文献类型:   Article
  • 作  者:   WANG L, YANG R, LI JJ, QU LB, HARRINGTON PD
  • 作者关键词:   graphene, cetyltrimethylammonium bromide, znse qd, sudan i, electrochemical sensor
  • 出版物名称:   SENSORS ACTUATORS BCHEMICAL
  • ISSN:   0925-4005
  • 通讯作者地址:   Zhengzhou Univ
  • 被引频次:   17
  • DOI:   10.1016/j.snb.2015.03.034
  • 出版年:   2015

▎ 摘  要

In this work, a very sensitive electrochemical sensor for Sudan I was established based on nanohybrids of graphene-ZnSe quantum dots. Positively charged cetyltrimethyl-ammonium bromide (CTAB) functionalized graphene was used as a template-directed building block to self-assemble negatively charged ZnSe quantum dots (QDs). The hybrids of ZnSe-CTAB-graphene exhibited strong enrichment effect on Sudan I and gave superior electrocatalytic activity towards the oxidation of Sudan I. Applying differential pulse voltammetry (DPV), the peak current of Sudan I is proportional to its concentration in the range from 0.004 to 2.0 mu M and 2.0 to 15.0 mu M. This report is the first on applying graphene-ZnSe hybrids for electrochemical sensing. (C) 2015 Elsevier B.V. All rights reserved.