• 文献标题:   Process optimization of dye-sensitized solar cells using TiO2-graphene nanocomposites
  • 文献类型:   Article
  • 作  者:   SIWACH B, MOHAN D, SHARMA S, JYOTI D
  • 作者关键词:   tio2, graphene, nanocomposite, dssc, photoanode
  • 出版物名称:   BULLETIN OF MATERIALS SCIENCE
  • ISSN:   0250-4707 EI 0973-7669
  • 通讯作者地址:   Guru Jambheshwar Univ Sci Technol
  • 被引频次:   5
  • DOI:   10.1007/s12034-017-1492-z
  • 出版年:   2017

▎ 摘  要

TiO2-graphene (TGR) nanocomposites with varying concentrations of graphene from 0 to 1 wt% were prepared by direct mix method. X-ray diffraction (XRD) spectra confirmed the incorporation of graphene in photoanode material, which was further supported by field emission scanning electron microscopy (FESEM) and energy dispersive X-ray (EDX). The UV-visible spectrum of these nanocomposites shifted towards higher wavelength region as compared to pure TiO2 that indicated a reduced band gap and hence, enhanced absorption bandwidth. Significant reduction in electron-hole recombination was confirmed from photoluminescence spectroscopy. These TGR nanocomposite films after tethering with black dye were employed as photoanodes in dye-sensitized solar cells (DSSCs). The efficiency of solar cells at varying concentrations of graphene (in photoandes) was also investigated. TGR 0.25 wt% nanocomposite showed the highest photocurrent density (J(SC)) of 18.4 mA cm(-2) and efficiency (eta) of 4.69%.