• 文献标题:   Advanced model for conductivity estimation of graphene-based samples considering interphase effect, tunneling mechanism, and filler wettability
  • 文献类型:   Article
  • 作  者:   ZARE Y, RHEE KY
  • 作者关键词:   polymer graphene system, conductivity, interphase, surface energy, tunneling mechanism, network
  • 出版物名称:   JOURNAL OF INDUSTRIAL ENGINEERING CHEMISTRY
  • ISSN:   1226-086X EI 1876-794X
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.1016/j.jiec.2021.12.028 EA MAR 2022
  • 出版年:   2022

▎ 摘  要

In this study, we propose a model for the estimation of conductivity of graphene-based samples considering the roles of the interphase depth, filler portion in the nets, network efficiency, tunneling processes (as a quantum effects of graphene), and superficial energies of polymer and nanoparticles. This model considers the effects of the amount, dimensions, conduction, and percolation onset of graphene nanosheets on conductivity. The proposed model is evaluated using experimental data and parametric examinations. The outputs of the proposed model display a desirable agreement with experimental results. It is demonstrated that the interphase deepness, network efficiency, polymer surface energy, and graphene aspect ratio directly control the conductivity, and a superior conductivity is acquired by the slimmer tunnels, lower percolation onset, and lower filler surface energy.(c) 2021 The Korean Society of Industrial and Engineering Chemistry. Published by Elsevier B.V. All rights reserved.