▎ 摘　　要

HighlightsN, O co-doped graphene layered block (NOGB) was prepared as sulfur host for lithium-sulfur batteries.The NOGB/S shows good rate performance due to robust electrochemical kinetics.The strong physicochemical confinement leads to an improved cycling stability. AbstractThe development of lithium-sulfur batteries (LSBs) is restricted by their poor cycle stability and rate performance due to the low conductivity of sulfur and severe shuttle effect. Herein, an N, O co-doped graphene layered block (NOGB) with many dents on the graphene sheets is designed as effective sulfur host for high-performance LSBs. The sulfur platelets are physically confined into the dents and closely contacted with the graphene scaffold, ensuring structural stability and high conductivity. The highly doped N and O atoms can prevent the shuttle effect of sulfur species by strong chemical adsorption. Moreover, the micropores on the graphene sheets enable fast Li+ transport through the blocks. As a result, the obtained NOGB/S composite with 76 wt% sulfur content shows a high capacity of 1413 mAh g(-1) at 0.1 C, good rate performance of 433 mAh g(-1) at 10 C, and remarkable stability with 526 mAh g(-1) at after 1000 cycles at 1 C (average decay rate: 0.038% per cycle). Our design provides a comprehensive route for simultaneously improving the conductivity, ion transport kinetics, and preventing the shuttle effect in LSBs.