• 文献标题:   Enhanced Catalytic Activity for CO Oxidation by Highly Active Pd Nanoparticles Supported on Reduced Graphene Oxide/Copper Metal Organic Framework
  • 文献类型:   Article
  • 作  者:   ALTASS HM, MORAD M, KHDER ARS, MANNAA MA, JASSAS RS, ALSIMAREE AA, AHMED SA, SALAMA RS
  • 作者关键词:   co oxidation, pd nanoparticle, rgo, cubtc, cumof199
  • 出版物名称:   JOURNAL OF THE TAIWAN INSTITUTE OF CHEMICAL ENGINEERS
  • ISSN:   1876-1070 EI 1876-1089
  • 通讯作者地址:  
  • 被引频次:   29
  • DOI:   10.1016/j.jtice.2021.08.034 EA OCT 2021
  • 出版年:   2021

▎ 摘  要

As a result of the increase in industrial activities and the extensive use of automobiles, air pollutants, espe-cially carbon monoxide, reach the alarm level. The removal of carbon monoxide through oxidation is still oneof the best tactics so far. Therefore, looking for an active and durable catalyst is considered the key factor forimproving the oxidation process. In this work, Pd nanoparticles (1.0, 3.0 and 5.0 wt.%) were supported ontoreduced graphene oxide / copper metal organic framework nanocomposite (rGO@Cu-BTC) through one potsolvothermal synthesis method. The catalysts were thoroughly characterized by state-of-the-art techniquessuch as XPS, SEM, TEM, XRD, N2physisorption, and FT-IR. The results revealed that the Pd nanoparticleswere exceptionally dispersed on rGO@Cu-BTC nanocomposite surface and the Cu-BTC crystals showed excel-lent octahedral structure with smooth edges as indicated SEM images. The results revealed that 3.0 wt. % Pd/rGO@Cu-BTC acts as an excellent catalyst in the CO oxidation as indicated by T50and T100values of 71 and82 degrees C, respectively. Additionally, the results showed that rGO has a vital role in the dispersion of Pd NPs onthe catalyst surface as well as the presence of surface oxygen groups, which yields higher catalytic activitycompared with the catalyst without rGO. (c) 2021 Taiwan Institute of Chemical Engineers. Published by Elsevier B.V. All rights reserve