• 文献标题:   Zeolite-templated carbons - three-dimensional microporous graphene frameworks
  • 文献类型:   Review
  • 作  者:   NISHIHARA H, KYOTANI T
  • 作者关键词:  
  • 出版物名称:   CHEMICAL COMMUNICATIONS
  • ISSN:   1359-7345 EI 1364-548X
  • 通讯作者地址:   Tohoku Univ
  • 被引频次:   20
  • DOI:   10.1039/c8cc01932k
  • 出版年:   2018

▎ 摘  要

Zeolite-templated carbons (ZTCs) are ordered microporous carbons synthesized by using zeolite as a sacrificial template. Unlike well-known ordered mesoporous carbons obtained by using mesoporous silica templates, ZTCs consist of curved and single-layer graphene frameworks, thereby affording uniform micropore size (ca. 1.2 nm), developed microporosity (similar to 1.7 cm(3) g(-1)), very high surface area (similar to 4000 m(2) g(-1)), good compatibility with chemical modification, and remarkable softness/elasticity. Thus, ZTCs have been used in many applications such as hydrogen storage, methane storage, CO2 capture, liquid-phase adsorption, catalysts, electrochemical capacitors, batteries, and fuel cells. Herein, the relevant research studies are summarized, and the properties as well as the performances of ZTCs are compared with those of other materials including metal-organic frameworks, to elucidate the intrinsic advantages of ZTCs and their future development.