• 文献标题:   Anisotropic thermal conductivity and electromagnetic interference shielding of epoxy nanocomposites based on magnetic driving reduced graphene oxide@Fe3O4
  • 文献类型:   Article
  • 作  者:   LIU YC, LU MP, WU K, YAO S, DU XX, CHEN GK, ZHANG Q, LIANG LY, LU MG
  • 作者关键词:   graphene, magnetic field, thermal conductivity, electromagnetic interference emi shielding
  • 出版物名称:   COMPOSITES SCIENCE TECHNOLOGY
  • ISSN:   0266-3538 EI 1879-1050
  • 通讯作者地址:   Chinese Acad Sci
  • 被引频次:   27
  • DOI:   10.1016/j.compscitech.2019.02.005
  • 出版年:   2019

▎ 摘  要

Highly thermal conductive materials with excellent electromagnetic interference (EMI) shielding efficiency have been attracted much attention in the field of modem electronic devices. In this work, the magnetic reduced graphene oxide (RGO)@Fe3O4 nanoplatelets (NPs), which were acted as fillers, were fabricated via electrostatic self-assembly and co-precipitation technique. The nanocomposites were prepared by applying external magnetic fields to align RGO@Fe3O4 NPs during epoxy curing. Owing to external magnetic fields and the anisotropic properties of RGO@Fe3O4 NPs, the nanocomposite with aligned RGO@Fe3O4 NPs exhibited an anisotropic thermal conductivity(lambda). For the in-plane (parallel to) direction, lambda(parallel to) as high as 1.213 W m(-1) K-1, which was higher than that of through-plane (perpendicular to), and the anisotropy index (lambda(parallel to/)lambda(perpendicular to)) was 15.96. Meanwhile, the resulting sample possessed excellent thermal stability and an electromagnetic interference (EMI) shielding of 13.45 dB at 8.2 GHz. Overall, aligning RGO@Fe3O4 NPs under magnetic field enhanced the interaction among RGO@Fe3O4 NPs in in plane direction, so as to promote the formation of thermal conductive networks in the horizontal direction with leading to anisotropic lambda. Furthermore, its contributed to electromagnetic shielding effectiveness, and the dominant EMI shielding mechanism is the reflection.