• 文献标题:   Free-Surfactant Synthesis of Graphene-Layered Carbon Composite and Its Utilization for Electrocatalysis
  • 文献类型:   Article
  • 作  者:   MUKAWA K, OYAMA N, SHINMI T, SEKINE Y
  • 作者关键词:  
  • 出版物名称:   BULLETIN OF THE CHEMICAL SOCIETY OF JAPAN
  • ISSN:   0009-2673 EI 1348-0634
  • 通讯作者地址:   Waseda Univ
  • 被引频次:   13
  • DOI:   10.1246/bcsj.20160137
  • 出版年:   2016

▎ 摘  要

We synthesized a characteristic graphene-layered carbon particle composite using pyrolysis of hydrocarbon in an electric field and consecutive activation treatment under CO2 atmosphere. TEM, N-2 adsorption isotherm, Raman spectroscopy, and XPS revealed structural features of this unique composite. Graphenes and carbon particles in the resultant composite are combined homogeneously in nanoscale with a mesoscale structure and with high carbon purity. When Pt nanoparticles are loaded on the composite, they show high performance as an electrocatalyst because of their higher electrochemical active surface area and higher durability against the sintering of Pt nanoparticles. Resulting material is a multifunctional composite by virtue of its nanostructural features.