• 文献标题:   Graphene oxide wrapped hierarchical porous carbon-sulfur composite cathode with enhanced cycling and rate performance for lithium sulfur batteries
  • 文献类型:   Article
  • 作  者:   LIU SK, XIE K, LI YJ, CHEN ZX, HONG XB, ZHOU LJ, YUAN JF, ZHENG CM
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Natl Univ Def Technol
  • 被引频次:   21
  • DOI:   10.1039/c4ra12393j
  • 出版年:   2015

▎ 摘  要

A graphene oxide sheet wrapped hierarchical porous carbon-sulfur (HPC-S@GO) composite was designed by a two-step method to improve the lithium sulfur battery performance. With this nanostructure design, the hierarchical porous carbon supplies an electronic transport pathway and provides a large pore volume to load the sulfur while the encapsulated graphene oxide sheet is effective in trapping sulfur and polysulfides during cycling. The obtained HPC-S@GO composite delivers prolonged cycling stability and an enhanced rate performance: the capacity fading is 0.12% per cycle over 400 cycles at 1 C (1672 mA g(-1)) rate, and the capacities at 0.2, 0.5, 1, 2 and 5 C rate are 1333.3, 896.9, 763.0, 669.5 and 505.6 mA h g(-1), respectively.