• 文献标题:   Nitrogen/oxygen dual-doped hierarchically porous carbon/graphene composite as high-performance anode for potassium storage
  • 文献类型:   Article
  • 作  者:   ZHU YY, WANG MY, ZHANG Y, WANG R, ZHANG YT, WANG CY
  • 作者关键词:   nitrogen/oxygen dualdoping, porous structure, conductive network, potassiumion batterie, potassiumion capacitor
  • 出版物名称:   ELECTROCHIMICA ACTA
  • ISSN:   0013-4686 EI 1873-3859
  • 通讯作者地址:  
  • 被引频次:   5
  • DOI:   10.1016/j.electacta.2021.138093 EA MAR 2021
  • 出版年:   2021

▎ 摘  要

Although potassium-ion batteries (PIBs) are considered as promising candidate to lithum-ion batteries (LIBs) in the area where energy density is no longer the top priority, developing suitable anodes for PIBs is still a big challenge because of the large radius of potassium-ion, which limits the rate performace and cyclic stability. Herein, nitrogen/oxygen dual-doped hierarchically porous carbon/graphene composite (NOPC@G) has been prepared for potassium-ion storage. Thanks to the heteroatom-rich porous structure and conductive network induced by graphene, the ion diffusion and electronic transmission are enhanced, which make NOPC@G exhibit outstanding potassium storage performance in terms of high specific capacity (445 mAhg(-1)), high rate capability (112 mAhg(-1) at 40 C) and excellent cyclic stability. Furthermore, when used as anode for potassium-ion capacitors (PICs), NOPC@G also exhibits an impressive electrochemical performance with a maximum energy density of 153 Wh kg(-1) (with a power density of 120 W kg(-1)) and a maximum power density of 22.98 kW kg(-1) (with an energy density of 57 Wh kg(-1)). The simple synthesis route combined with the desirable electrochemical performance makes NOPC@G a promising anode for potassium storage. (C) 2021 Elsevier Ltd. All rights reserved.