• 文献标题:   Reduction and Functionalization of Graphene Oxide Sheets Using Biomimetic Dopamine Derivatives in One Step
  • 文献类型:   Article
  • 作  者:   KAMINSKA I, DAS MR, COFFINIER Y, NIEDZIOLKAJONSSON J, SOBCZAK J, WOISEL P, LYSKAWA J, OPALLO M, BOUKHERROUB R, SZUNERITS S
  • 作者关键词:   graphene, dopamine, reduction, click chemistry, electrochemistry, azide function
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244 EI 1944-8252
  • 通讯作者地址:   Univ Lille 1
  • 被引频次:   137
  • DOI:   10.1021/am201664n
  • 出版年:   2012

▎ 摘  要

An easy and environmentally friendly chemical method for the simultaneous reduction and noncovalent functionalization of graphene oxide (GO) using dopamine derivatives is. described. The reaction takes place at room temperature, under ultrasonication of an aqueous suspension of GO and a dopamine derivative. X-ray photoelectron spectroscopy, FT-IR spectroscopy, and cyclic voltammetry characterizations revealed that the resulting material consists of graphene functionalized with the dopamine derivative. This one-step protocol is applied for simultaneous reduction and functionalization of graphene oxide with a dopamine derivative bearing an azide function. The chemical reactivity of the azide function was demonstrated by a postfunctionalization with ethynylferrocene using the Cu(I) catalyzed 1,3-dipolar cyloaddition.