• 文献标题:   Improvement of Mechanical Properties and Solvent Resistance of Polyurethane Coating by Chemical Grafting of Graphene Oxide
  • 文献类型:   Article
  • 作  者:   LIANG GT, YAO FB, QI YR, GONG RZ, LI R, LIU BX, ZHAO YY, LIAN CL, LI LM, DONG XY, LI YF
  • 作者关键词:   waterborne polyurethane, mechanical performance, chemical resistance, graphene oxide, chemical graft, wood coating
  • 出版物名称:   POLYMERS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.3390/polym15040882
  • 出版年:   2023

▎ 摘  要

Waterborne polyurethane coatings (WPU) are widely used in various types of coatings due to their environmental friendliness, rich gloss, and strong adhesion. However, their inferior mechanical properties and solvent resistance limit their application on the surface of wood products. In this study, graphene oxide (GO) with nanoscale size, large surface area, and abundant functional groups was incorporated into WPU by chemical grafting to improve the dispersion of GO in WPU, resulting in excellent mechanical properties and solvent resistance of WPU coatings. GO with abundant oxygen-containing functional groups and nanoscale size was prepared, and maintained good compatibility with WPU. When the GO concentration was 0.7 wt%, the tensile strength of GO-modified WPU coating film increased by 64.89%, and the abrasion resistance and pendulum hardness increased by 28.19% and 15.87%, respectively. In addition, GO also improved the solvent resistance of WPU coatings. The chemical grafting strategy employed in this study provides a feasible way to improve the dispersion of GO in WPU and provides a useful reference for the modification of waterborne wood coatings.