• 文献标题:   In situ synthesis of graphene/cobalt nanocomposites and their magnetic properties
  • 文献类型:   Article
  • 作  者:   JI ZY, SHEN XP, SONG Y, ZHU GX
  • 作者关键词:   graphene, cobalt, synthesi, nanocomposite, magnetic propertie
  • 出版物名称:   MATERIALS SCIENCE ENGINEERING BADVANCED FUNCTIONAL SOLIDSTATE MATERIALS
  • ISSN:   0921-5107 EI 1873-4944
  • 通讯作者地址:   Jiangsu Univ
  • 被引频次:   64
  • DOI:   10.1016/j.mseb.2011.02.026
  • 出版年:   2011

▎ 摘  要

Graphene, which possesses unique nanostructure and excellent properties, is considered as a low cost alternative to carbon nanotubes in nanocomposites. In this study, we present a simple in situ approach for the deposition of cobalt (Co) nanoparticles onto surfaces of graphene sheets by hydrazine hydrate reduction. The as-synthesized composites were characterized by X-ray diffraction (XRD), Fourier transform infrared (FT-IR) spectroscopy, Raman spectroscopy, transmission electron microscopy (TEM) and thermogravimetry and differential scanning calorimetry. It was shown that the as-formed Co nanoparticies were densely and homogeneously deposited on the surfaces of the graphene sheets and as a result, the restacking of the as-reduced graphene sheets was effectively inhibited. Magnetic studies reveal that the graphene/Co nanocomposite displays ferromagnetic behavior with saturation magnetizations of 53.4 emu g(-1), remanent magnetization of 6.0 emu g(-1) and coercivity of 226 Oe at room temperature, which make it promising for practical applications in future nanotechnology. (C) 2011 Elsevier B.V. All rights reserved.