• 文献标题:   Electrochemical Performance of Graphene Oxide/Black Arsenic Phosphorus/Carbon Nanotubes as Anode Material for LIBs
  • 文献类型:   Article
  • 作  者:   HOU YY, MA SF, XU Y, ZHANG S, HAO XD, XU BS
  • 作者关键词:   black arsenic phosphoru, 2d material, carbon nanotube, lithiumion batterie
  • 出版物名称:   MATERIALS
  • ISSN:  
  • 通讯作者地址:  
  • 被引频次:   1
  • DOI:   10.3390/ma15134576
  • 出版年:   2022

▎ 摘  要

As a new two-dimensional material, black arsenic phosphorus (B-AsP) has emerged as a promising electrode for lithium-ion batteries (LIBs) due to its large theoretical capacity and ability to absorb large amounts of Li atoms. However, the poor electronic conductivity and large volume expansion during the lithiation/delithiation process have largely impeded the development of B-AsP electrodes. In this study, graphene oxide (GO)/B-AsP/carbon nanotubes (CNTs) with remarkable lithium-storage property were fabricated via CVD and ultrasound-assisted method. The electrochemical behavior of the GO/B-AsP/CNTs was investigated as an anode in lithium-ion batteries. From the results, as a new-type anode for LIBs, GO/B-AsP/CNTs composite demonstrated a stable capacity of 1286 and 339 mA h g(-1) at the current density of 0.1 and 1 A g(-1), respectively. The capacity of GO/B-AsP/CNTs was 693 mA h g(-1) after 50 cycles, resulting in capacity retention of almost 86%. In addition, the stable P-C and As-C bonds were formed between B-AsP, GO, and CNTs. Thus, volume expansion of B-AsP was alleviated and the capacity was increased due to the confining effect of GO and CNTs.