• 文献标题:   Synthesis and characterization of poly(butylene succinate)-reduced graphene oxide composite through in-situ melt polymerization
  • 文献类型:   Article
  • 作  者:   KOO JM, PARK H, HWANG SY, HAN TH, IM SS
  • 作者关键词:   polybutylene succinate, reduced graphene oxide, bioplastic, polymer composite
  • 出版物名称:   JOURNAL OF POLYMER RESEARCH
  • ISSN:   1022-9760 EI 1572-8935
  • 通讯作者地址:   Hanyang Univ
  • 被引频次:   1
  • DOI:   10.1007/s10965-017-1361-x
  • 出版年:   2017

▎ 摘  要

Reduced graphene oxide (rGO) was selected as a reinforcing filler to be incorporated in Polybutylene succinate (PBS) through in-situ melt polymerization where enhancing and interesting properties were observed. Dispersed rGO showed no chemical interaction with PBS matrix by showing constant glass transition temperature (T-g) and melting temperature (T-m) but clear indication of physical interaction was observed in increased tensile strength and elongation. With only 0.1 wt% of rGO, the tensile strength and the elongation at break were increased by 80% and 373%, respectively, compared to neat PBS. Regarding crystallization behavior of synthesized composites, thermal conducting effect of rGO was revealed to have an impact on crystallization process. Furthermore, through wide-angle X-ray diffraction (XRD), the rGO functioned as a defect during crystallization and affected (021) and (020).