• 文献标题:   A Molecularly Imprinted Polymer with Incorporated Graphene Oxide for Electrochemical Determination of Quercetin
  • 文献类型:   Article
  • 作  者:   SUN S, ZHANG MQ, LI YJ, HE XW
  • 作者关键词:   molecularly imprinted polymer, graphene oxide, quercetin, modified electrode
  • 出版物名称:   SENSORS
  • ISSN:   1424-8220
  • 通讯作者地址:   Nankai Univ
  • 被引频次:   54
  • DOI:   10.3390/s130505493
  • 出版年:   2013

▎ 摘  要

The molecularly imprinted polymer based on polypyrrole film with incorporated graphene oxide was fabricated and used for electrochemical determination of quercetin. The electrochemical behavior of quercetin on the modified electrode was studied in detail using differential pulse voltammetry. The oxidation peak current of quercetin in B-R buffer solution (pH = 3.5) at the modified electrode was regressed with the concentration in the range from 6.0 x 10(-7) to 1.5 x 10(-5) mol/L (r(2) = 0.997) with a detection limit of 4.8 x 10(-8) mol/L (S/N = 3). This electrode showed good stability and reproducibility. In the above mentioned range, rutin or morin which has similar structures and at the same concentration as quercetin did not interfere with the determination of quercetin. The applicability of the method for complex matrix analysis was also evaluated.