• 文献标题:   Electrocatalytic synthesis of poly(2,6-diaminopyridine) on reduced graphene oxide and its application in glucose sensing
  • 文献类型:   Article
  • 作  者:   QIN Y, YUAN J, MA JF, KONG Y, XUE HG, PENG YG
  • 作者关键词:  
  • 出版物名称:   RSC ADVANCES
  • ISSN:   2046-2069
  • 通讯作者地址:   Changzhou Univ
  • 被引频次:   4
  • DOI:   10.1039/c5ra07345f
  • 出版年:   2015

▎ 摘  要

Reduced graphene oxide (RGO) was prepared via electrochemical reduction of graphene oxide (GO), and it can effectively catalyze the polymerization of 2,6-diaminopyridine. Poly(2,6-diaminopyridine) (PDAP) deposited on RGO (PDAP-RGO) has good electroactivity in a wide pH range until pH 11.0. Due to the electrocatalytic reduction of H2O2 at the PDAP-RGO, a platform for glucose sensing was constructed by immobilizing glucose oxidase (GOD) into the PDAP-RGO. The proposed glucose sensor exhibited a wide linear range from 0.05 to 6.65 mM, a low detection limit of 0.142 mu M, a good reproducibility and stability. The apparent Michaelis-Menten constant of GOD was also calculated based on the relationship between steady-state current and glucose concentration.