• 文献标题:   SnO2/graphene composite as highly reversible anode materials for lithium ion batteries
  • 文献类型:   Article
  • 作  者:   GUO Q, ZHENG Z, GAO HL, MA J, QIN X
  • 作者关键词:   tin oxide, graphene, composite, lithiumion batterie
  • 出版物名称:   JOURNAL OF POWER SOURCES
  • ISSN:   0378-7753 EI 1873-2755
  • 通讯作者地址:   Tianjin Univ
  • 被引频次:   99
  • DOI:   10.1016/j.jpowsour.2013.03.116
  • 出版年:   2013

▎ 摘  要

Tin oxide (SnO2)/graphene composite is synthesized via a simple wet chemical method using graphene oxide and SnCl2 center dot 2H(2)O as raw materials. Graphene of high reduction degree in the composite can provide high conductivity and large-current discharge capacity. SnO2 nanoparticles with dimension around 5 nm are uniformly distributed on the graphene matrix. The SnO2/graphene composite exhibits outstanding electrochemical performance such as high reversible capacities, good cycling stability and excellent high-rate discharge performance. The initial discharge and charge capacities are 1995.8 mAh g(-1) and 1923.5 mAh g(-1), respectively. After 40 cycles, the reversible discharge capacity is still maintained at 1545.7 mAh g(-1) at the current density of 1 A g(-1), indicating that the composite is a promising alternative anode material used for high-storage lithium ion batteries. Crown Copyright (C) 2013 Published by Elsevier B.V. All rights reserved.