• 文献标题:   Removal of dye by carboxymethyl cellulose, acrylamide and graphene oxide via a free radical polymerization process
  • 文献类型:   Article
  • 作  者:   VARAPRASAD K, JAYARAMUDU T, SADIKU ER
  • 作者关键词:   carboxymethyl cellulose, graphene oxide, hydrogel, dye removal
  • 出版物名称:   CARBOHYDRATE POLYMERS
  • ISSN:   0144-8617 EI 1879-1344
  • 通讯作者地址:   CIPA
  • 被引频次:   33
  • DOI:   10.1016/j.carbpol.2017.01.094
  • 出版年:   2017

▎ 摘  要

Carboxymethyl cellulose has been used for the design of novel engineered hydrogels in order to obtain effective three-dimensional structures for industrial applications. In this work, dye removal carboxymethyl cellulose-acrylamide-graphene oxide (CMC-AM-GO), hydrogels were prepared by a free-radical polymerization method. The GO was developed by the modified Hummers method. The CMC-AM-GO and GO were characterized by FTIR, XRD and SEM. The swelling and swelling kinetics were calculated using gravimetric process. The kinetic parameter, swelling exponent values [n = 0.59-0.7507] explained the fact that the CMC-AM-GO hydrogles have super Case II diffusion transport mechanism. CMCx-AM-GO (x = 1-4) and CMC-AM hydrogels were used for removal of Acid Blue-133. The result explains that composite hydrogels significantly removed the acid blue when compared to the neat hydro gel. The maximum AB absorption (185.45 mg/g) capacity was found in the case of CMC2-AM-GO hydrogel. Therefore, cellulose-based GO hydrogels can be termed as smart systems for the abstraction of dye in water purification applications. (C) 2017 Elsevier Ltd. All rights reserved.