• 文献标题:   High-throughput fabrication of strutted graphene by ammonium-assisted chemical blowing for high-performance supercapacitors
  • 文献类型:   Article
  • 作  者:   JIANG XF, WANG XB, DAI PC, LI X, WENG QH, WANG X, TANG DM, TANG J, BANDO Y, GOLBERG D
  • 作者关键词:   three dimensional graphene, strutted graphene, chemical blowing, supercapacitor
  • 出版物名称:   NANO ENERGY
  • ISSN:   2211-2855 EI 2211-3282
  • 通讯作者地址:   Natl Inst Mat Sci
  • 被引频次:   42
  • DOI:   10.1016/j.nanoen.2015.06.008
  • 出版年:   2015

▎ 摘  要

Three dimensional graphenes are most desired to deliver the unique nano-sized properties of graphenes to the macro-scale, yet their practical production remains insufficient. Herein we establish a general synthesis approach, i.e. ammonium-assisted chemical blowing via foaming sucrose into the bubble networks of sucrose-derived polymers, to effectively produce three dimensional strutted graphenes (SGs). SG consists of interconnected mono-/few-layered graphene membranes scaffolded by graphitic struts without restacking or agglomeration, which thus fully exposes the huge surface and possesses appropriate porosity. The SG is further applied as additive/binder-free electrodes for supercapacitors, which realize the high energy density of 50W h kg(-1) and the high maximum-power-density of 340 kW kg(-1) due to the large surface area, excellent interconnectivity and porosity. The mass-produced self-supporting SG would open up a wide horizon and enable the abundant potentials of graphenes for promising large-scale applications. (C) 2015 Elsevier Ltd. All rights reserved.