• 文献标题:   Conductive Graphene-Melamine Sponge Prepared via Microwave Irradiation
  • 文献类型:   Article
  • 作  者:   LIU WL, JIANG HB, RU Y, ZHANG XH, QIAO JL
  • 作者关键词:   nitrogendoping, graphenemelamine sponge, microwave reduction, conductivity, superhydrophobic, oil absorption
  • 出版物名称:   ACS APPLIED MATERIALS INTERFACES
  • ISSN:   1944-8244
  • 通讯作者地址:   Beijing Univ Chem Technol
  • 被引频次:   12
  • DOI:   10.1021/acsami.8b06070
  • 出版年:   2018

▎ 摘  要

A conductive graphene-melamine sponge (MS) prepared via microwave irradiation is reported in this paper. Graphene oxide supported on the MS was prereduced first at 100 degrees C and then further reduced in a household microwave oven at over 1000 degrees C. It was surprising to find that graphene oxide on the MS was reduced perfectly while the three-dimensional structure of the MS was kept well after high-temperature reduction via microwave irradiation. Slight pyrolysis of MS was also found during 5 s microwave irradiation, resulting in nitrogen generation from the pyrolysis of the MS being doped into graphene, which could benefit the electric conductivity of the prepared graphene-MS. The electric conductivity of the prepared graphene-MS is about 0.12-1.0 S/m because of the high reduction degree of graphene oxide and nitrogen doping. On the other hand, different from the pure MS, the newly developed conductive graphene-MS possesses superhydrophobic and superoleophilic properties. Overall, the newly developed conductive graphene-MS contained 94.3 wt % MS and 5.7 wt % N-doped graphene and is a cost-effective material with good elasticity, high conductivity, superhydrophobicity, and superoleophilicity.