• 文献标题:   Highly efficient hydrogen generation from hydrous hydrazine using a reduced graphene oxide-supported NiPtP nanoparticle catalyst
  • 文献类型:   Article
  • 作  者:   LIU T, YU JH, BIE HY, HAO ZR
  • 作者关键词:   niptp catalyst, graphene, dehydrogenation, hydrous hydrazine
  • 出版物名称:   JOURNAL OF ALLOYS COMPOUNDS
  • ISSN:   0925-8388 EI 1873-4669
  • 通讯作者地址:   Qingdao Univ Sci Technol
  • 被引频次:   9
  • DOI:   10.1016/j.jallcom.2016.08.113
  • 出版年:   2017

▎ 摘  要

Ultrafine NiPtP nanoparticles (NPs) assembled on reduced graphene oxide (rGO) have been synthesized by a co-reduction route using sodium hypophosphite (NaH2PO2) as the source of the nonmetallic P. The well-dispersed ultrafine NiPtP NPs with a diameter about 2 nm can be readily obtained. It is found that these catalysts demonstrate high selectivity and excellent catalytic activity for the decomposition of N2H4 center dot H2O at mild temperature. The enhanced catalytic performance can be attributed to synergistic effect of P-doping and strong high selectivity interaction with graphene support. (C) 2016 Elsevier B.V. All rights reserved.