• 文献标题:   Fabrication of Pt nanoparticles on ethylene diamine functionalized graphene for formic acid electrooxidation
  • 文献类型:   Article, Proceedings Paper
  • 作  者:   ZHONG XX, WANG ZH, HUANG YG, YU YH, FENG QP, LI QY
  • 作者关键词:   graphene, ethylene diamine, formic acid, electrocatalytic oxidation
  • 出版物名称:   INTERNATIONAL JOURNAL OF HYDROGEN ENERGY
  • ISSN:   0360-3199 EI 1879-3487
  • 通讯作者地址:   Guangxi Normal Univ
  • 被引频次:   12
  • DOI:   10.1016/j.ijhydene.2014.03.208
  • 出版年:   2014

▎ 摘  要

A novel and simple synthesis method of preparing ethylene diamine (ED) functionalized graphene (ED-Gh) decorated with Pt nanoparticle has been reported. Morphology, microstructure of the resulted material was characterized by scanning electron microscopy (SEM), transmission electron microscopy (TEM), Raman spectroscopy (Raman), X-ray photoelectron spectroscopy (XPS) and X-ray diffraction (XRD). Electrochemical studies to-ward formic acid electrooxidation were investigated by cyclic voltammetry (CV) and chronoamperometry (CA). These results showed that Pt nanoparticle with the crystallite size of about 5 nm was highly dispersed on ED-Gh and the catalyst exhibited good electro-catalytic activity and long-term stability. Therefore, ED-Gh can be a potential support for Pt in direct formic acid fuel cells. Copyright (C) 2014, Hydrogen Energy Publications, LLC. Published by Elsevier Ltd. All rights reserved.