• 文献标题:   Hydrothermal synthesis of flower-like NiS-Ni3S4/stereotaxically constructed graphene composite for ultrahigh-rate sodium storage
  • 文献类型:   Article
  • 作  者:   CHEN W, NING Y, LI QZ, LI KT, WU XH, WU WW, ZHANG HX
  • 作者关键词:   nisni3s4, stereotaxically constructed graphene, anode material, composite material, xray technique
  • 出版物名称:   MATERIALS LETTERS
  • ISSN:   0167-577X EI 1873-4979
  • 通讯作者地址:   Guangxi Univ
  • 被引频次:   4
  • DOI:   10.1016/j.matlet.2018.11.013
  • 出版年:   2019

▎ 摘  要

Flower-like NiS-Ni3S4/stereotaxically constructed graphene (NiS-Ni3S4/SCG) composite is synthesized by a hydrothermal method. When evaluated as anode materials for sodium ion battery, the material still retains a discharge capacity of 322.9 mA h g(-1) with a coulombic efficiency near 100% after 2000 cycles at 10 A g(-1), which corresponds to 69.2% of the 2nd discharge capacity. It is found that the SCG plays a positive role in improving electrochemical performance of NiS-Ni3S4 because it serves as an efficient 3D conductive network to enhance electronic conductivity and an elastic matrix to buffer volume expansion. (C) 2018 Elsevier B.V. All rights reserved.