• 文献标题:   Preparation and characterization of functionalized graphene oxide Cu (I) complex: A facile and reusable nanocatalyst for microwave assisted heterocyclization of alkyl halides with alkynes and sodium azide
  • 文献类型:   Article
  • 作  者:   NAEIMI H, SHAABANI R
  • 作者关键词:   graphene oxide, 1 2 3triazole, heterogeneous catalyst, microwave irradiation three component
  • 出版物名称:   CATALYSIS COMMUNICATIONS
  • ISSN:   1566-7367 EI 1873-3905
  • 通讯作者地址:   Univ Kashan
  • 被引频次:   2
  • DOI:   10.1016/j.catcom.2016.08.034
  • 出版年:   2016

▎ 摘  要

In this research, preparation of functionalized graphene oxide copper (I) complex first involves a reaction of carboxylic groups on graphene oxide with the amino groups on 1,7-heptandiamine and isotoic anhydride, and subsequently treatment with copper iodide. The formed complex was characterized by Fourier transform infrared spectroscopy (FT-IR), X-ray diffraction spectroscopy (XRD), energy dispersive X-ray (EDX) and field emission scanning electron microscopy (FE-SEM) techniques. 1,2,3-triazoles were synthesized from reaction of alkyl halides, alkynes and sodium azide catalyzed by functionalized graphene oxide copper (I) complex under microwave irradiation in excellent yields. This procedure eliminates the need to handle organic azides. (C) 2016 Elsevier B.V. All rights reserved.