• 文献标题:   CVD growth of large area and uniform graphene on tilted copper foil for high performance flexible transparent conductive film
  • 文献类型:   Article
  • 作  者:   ZHANG J, HU PA, WANG XN, WANG ZL, LIU DQ, YANG B, CAO WW
  • 作者关键词:  
  • 出版物名称:   JOURNAL OF MATERIALS CHEMISTRY
  • ISSN:   0959-9428 EI 1364-5501
  • 通讯作者地址:   Harbin Inst Technol
  • 被引频次:   51
  • DOI:   10.1039/c2jm33881e
  • 出版年:   2012

▎ 摘  要

This study has been performed on the synthesis of a large area, uniform graphene film on tilted copper foil against gaseous flow in a chemical vapor deposition (CVD) system. The copper foil on which the graphene grows is tilted against gaseous flow in the CVD process, which promotes the uniformity of graphene due to geometrical fluidic dynamics. The uniform graphene film with grain size up to ten micrometers and few defects has been synthesized on copper foils using optimized parameters including growth time, methane concentration and growth temperature. Field effect transistors made of the grown graphene show high carrier mobilities of 5080.5 cm(2) V-1 s(-1), indicating fine quality graphene. These uniform graphenes can be used as high performance, flexible transparent conductors, which show improved tradeoff between conductivity and transparency: the transmittance of 96.5% at 550 nm with sheet resistance of similar to 600 Omega sq(-1), and the transmittance of 86.7% at 550 nm with sheet resistance of similar to 400 Omega sq(-1).