▎ 摘 要
A smart strategy for the synthesis of hierarchical CoAl-LDH hollow spheres assembled with nitrogen and sulfur co-doped graphene for high holding of palladium nanoparticles (CoAl-LDH@N,S-G@Pd) is reported. This architecture exhibited excellent activity in Heck reactions with TOF as high as 1633 h(-1) due to a strong metal-support interaction, good electron transfers and high surface area.