• 文献标题:   VOPO4 center dot 2H(2)O encapsulated in graphene oxide as a heterogeneous catalyst for selective hydroxylation of benzene to phenol
  • 文献类型:   Article
  • 作  者:   BORAH P, DATTA A, NGUYEN KT, ZHAO YL
  • 作者关键词:  
  • 出版物名称:   GREEN CHEMISTRY
  • ISSN:   1463-9262 EI 1463-9270
  • 通讯作者地址:   Nanyang Technol Univ
  • 被引频次:   27
  • DOI:   10.1039/c5gc01194a
  • 出版年:   2016

▎ 摘  要

A novel heterogeneous hybrid catalyst (VPO@GO) was prepared through a strong interaction between graphene oxide (GO) and exfoliated VOPO4 center dot 2H(2)O. V4+-rich VPO@GO can selectively oxidize benzene to phenol at 60 degrees C using H2O2 as the oxidant, affording 100% selectivity with a benzene conversion of similar to 33% up to 5 catalytic cycles.